Article ID Journal Published Year Pages File Type
1411942 Journal of Molecular Structure 2007 5 Pages PDF
Abstract
From the reaction of tribenzo-S2O2 macrocyclic ligand (L1) and silver picrate (AgPic), a unique binuclear complex [Ag2(L1)2(Pic)2] (1) has been obtained. The species 1 has been characterised by single-crystal X-ray diffraction analysis providing a definitive proof of its cyclic dimer structure as well as the anion-ligand π-π stacking interactions between L1 and Pic−. The result of a comparative NMR experiment suggests that the solid structure of 1 is also retained in solution.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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