Article ID Journal Published Year Pages File Type
1411996 Journal of Molecular Structure 2006 9 Pages PDF
Abstract
Crystal structures of new tetrahalocuprate salts of α-isosparteine [(C15H28N2)2+xCuBr42-xH2O], 1 and [(C15H28N2)2+xCuCl42-xH2O], 2, as well as (-)sparteine [(C15H28N2)2+xCuCl42-xH2O], 3, were determined by X-ray diffraction. All three compounds crystallize as monohydrates and build identical hydrogen bonded chains involving water and tetrahalocuprate units, but differ in the configuration and conformation of the doubly protonated cationic species, and the way they pack in the crystal lattice, and interact with the complex counter anions. The IR, UV-vis, MS and EPR spectra were collected for 1 and 2. The magnetic properties of new compounds have been determined.
Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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