Article ID Journal Published Year Pages File Type
1412031 Journal of Molecular Structure 2006 4 Pages PDF
Abstract

Conventional solution method yields an interesting supramolecular complex—[(CMCR)(phen)3]·H2O (1) which was characterized by crystallography. The unique embed-buckle architecture was formed through intra- and/or intermolecular hydrogen bonds and C–H⋯π interactions between the host—C-methylcalix[4]resorcarene (CMCR) and guest—1,10-phenanthroline (phen). The extended conjugated system of (1) results in an enlarged cavity in host molecule and further to the enhanced fluorescent property.

Related Topics
Physical Sciences and Engineering Chemistry Organic Chemistry
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