| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1481744 | Journal of Non-Crystalline Solids | 2012 | 9 Pages |
Abstract
⺠Vanadate glasses in the system, xV2O5-(1 â x) As2O3, containing up to 42 mol% As2O3 were studied. ⺠V provides polarons (SP) and As provides bipolarons (SBP) for electrical conduction. ⺠SP hopping is the main mechanism of electrical conduction with minimal contribution from BP. ⺠Thermopower is negative for > 73 mol% V2O5 glasses and positive for others indicating influence of BPs. ⺠There is a change in the majority charge carrier around 70 mol% V2O5.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Sezhian Annamalai, Rudra P. Bhatta, Ian L. Pegg, Biprodas Dutta,