| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1482518 | Journal of Non-Crystalline Solids | 2011 | 5 Pages |
In this work, novel thiol-ene (TE)/hyperbranched polymer(HBP) hybrid thin films have been prepared by a simple photopolymerization method and the TE/HBP system was also investigated in terms of thermocuring behavior and gas barrier properties. The effect of added HBP on thermal curing (cross-linking) of TE polymer was examined with dynamic and isothermal differential scanning calorimeter (DSC) and compared with photocuring reaction of identical system. The structure of prepared TE/HBP hybrid thin film was analyzed by X-ray diffraction (XRD). Themomechanical analysis (TMA) provided extensive data on the coefficient of linear thermal expansion (CTE), dimensional change upon heating, and isothermal profile of TE/HBP hybrid thin films. Light transmittance as well as water/oxygen permeability of the resulting TE/HBP hybrid thin film was also measured depending on the HBP content.
► Novel transparent thiol-ene/hyperbranched polymer hybrid thin film. ► Successful photopolymerization of thiol-ene in the presence of HBP filler. ► Determination of process window for photopolymerization of thiol-ene depending on HBP content. ► Transparent thin film with enhanced thermal stability and improved gas permeation performance.
