Article ID Journal Published Year Pages File Type
1483157 Journal of Non-Crystalline Solids 2009 6 Pages PDF
Abstract
Transitions into, and out of intermediate phases (IPs) with minimal strain have been identified to date by Boolchand and co-workers, in bulk glasses, primarily by the extraordinary low values of the change in enthalpy, ΔHnr, associated with non-reversible heat flow, and by Lucovsky and coworkers in deposited thin films, and at dielectric-semiconductor interfaces by combining spectrographic characterizations, primarily synchrotron X-ray absorption and X-ray photoemission, and electrical measurements. This paper emphasizes chemical bonding self-organizations that minimize macroscopic strain within the IP windows, and identifies for the first time the necessary and sufficient conditions for IP windows to open, and to close, as a function of changes in the alloy composition. Percolation theory, and in particular competitive and synergistic double percolation provide a quantification of IP window first and second transition compositions that account for many of the experimentally determined IP window threshold transitions and IP window widths identified to date.
Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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