Article ID Journal Published Year Pages File Type
1484391 Journal of Non-Crystalline Solids 2005 5 Pages PDF
Abstract

A glass with the stoichiometry BaO · Al2O3 · B2O3 was melted from the raw materials. Three types of samples were prepared: (i) the as melted glass was thermally treated, (ii) the glass was powdered, pressed and thermally treated to obtain sinter glass–ceramics and (iii) the crushed glass was mixed with a platinum salt solution, remelted, cooled and then thermally treated. All three samples contained BaO · Al2O3 · B2O3 as crystalline phase and showed negative thermal expansion coefficients. However, those of as melted and crystallized sample was most and that of the sintered sample least negative. High temperature X-ray powder diffraction was performed in order to study the thermal expansion in different crystallographic directions. It is shown that thermal expansion is strongly negative in the crystallographic c-axis while it is positive with respect to the a-axis.

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Physical Sciences and Engineering Materials Science Ceramics and Composites
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