Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1485601 | Journal of Non-Crystalline Solids | 2006 | 7 Pages |
Abstract
Synthesis and devitrification behavior of Cr-doped CaO–GeO2–Li2O–B2O3(Al2O3) glasses have been studied. A range of glass compositions was found to yield transparent glass-ceramics after devitrification. The size of crystallites is below 1 μm. Glass-ceramic samples exhibit 1050–1600 nm broad-band emission with a maximum around 1260 nm, very similar to the emission of Cr4+:Ca2GeO4 bulk crystals. X-ray diffraction measurements indicate that the structure of crystallites exhibiting near infrared emission in glass-ceramics may be assigned to Cr4+:Ca2GeO4 with increased lattice parameters.
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
A.B. Bykov, M.Yu. Sharonov, V. Petricevic, I. Popov, L.L. Isaacs, J. Steiner, R.R. Alfano,