Article ID Journal Published Year Pages File Type
1485601 Journal of Non-Crystalline Solids 2006 7 Pages PDF
Abstract

Synthesis and devitrification behavior of Cr-doped CaO–GeO2–Li2O–B2O3(Al2O3) glasses have been studied. A range of glass compositions was found to yield transparent glass-ceramics after devitrification. The size of crystallites is below 1 μm. Glass-ceramic samples exhibit 1050–1600 nm broad-band emission with a maximum around 1260 nm, very similar to the emission of Cr4+:Ca2GeO4 bulk crystals. X-ray diffraction measurements indicate that the structure of crystallites exhibiting near infrared emission in glass-ceramics may be assigned to Cr4+:Ca2GeO4 with increased lattice parameters.

Related Topics
Physical Sciences and Engineering Materials Science Ceramics and Composites
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