Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1485708 | Journal of Non-Crystalline Solids | 2007 | 6 Pages |
Abstract
CuBr nanocrystallite-dispersed glasses were prepared by incorporation of copper into bromide ion-containing borosilicate glass using the technique of copper staining. The copper ion incorporation process was mainly controlled by ionic diffusion from the surface to the interior of the glass. The depth profiles of Cu and CuBr concentration were examined by energy dispersive X-ray analysis and by reference to the change in absorption intensity assigned to the CuBr exciton band along the depth. While the Cu concentration was found to decrease monotonically, the CuBr concentration profile showed a maximum at a distance of 10-50 μm from the glass surface. Although the depth reached by the copper ions became greater with increasing heat-treatment time, the depth at which CuBr was precipitated was found to be saturated. This means that regions were found in the glasses in which no CuBr crystallites precipitated, although migration of Cu ions to these regions had taken place.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
Kohei Kadono, Tatsuya Suetsugu, Takeshi Ohtani, Toshihiko Einishi, Takashi Tarumi, Tetsuo Yazawa,