Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1486242 | Journal of Non-Crystalline Solids | 2006 | 4 Pages |
Abstract
In this work, we report time-resolved line-narrowed fluorescence spectra of the 5D0 → 7F0−6 transitions of Eu3+-doped 40Bi2O3–40PbO–10Ga2O3–10GeO2 and 60GeO2–25PbO–15Nb2O5 glasses obtained at 10 K by using different resonant excitation wavelengths along the 7F0 → 5D0 transition. The wavelength dependence of the 7F1 splitting in both glasses suggests the existence of a broad distribution of Eu3+ centres possessing a variety of local field environments. The influence of the local coordination ions on the optical properties of Eu3+ has been studied by analysing the dependence of the crystal field (CF) parameters on the excitation energy along the 7F0 → 5D0 transition.
Keywords
Related Topics
Physical Sciences and Engineering
Materials Science
Ceramics and Composites
Authors
C. Cascales, R. Balda, J. Fernández, M.A. Arriandiaga, J.M. Fdez-Navarro,