The effect of neutron irradiation dose on vacancy defect accumulation and annealing in pure nickel

In order to investigate the dose dependence of vacancy defect evolution in nickel, specimens of high-purity Ni were neutron-irradiated at ∼330 K in the IVV-2M reactor (Russia) to fluencies in the range of 1 × 1021–1 × 1023 n/m2 (E > 0.1 MeV) corresponding to displacement dose levels in the range of about 0.0001–0.01 dpa and subsequently stepwise annealed to about 900 K. Ni was characterized both in as-irradiated state as well as after post-irradiation annealing by positron annihilation spectroscopy. The formation of three-dimensional vacancy clusters (3D-VCs) in cascades was observed under neutron irradiation, the concentration of 3D-VCs increases with increasing dose level. 3D-VCs collapse into secondary-type clusters (stacking fault tetrahedra (SFTs), and vacancy loops) during stepwise annealing at 350–450 K. It is shown that the thermal stability of SFTs grow with increasing dose level, probably, it is due to growth of the average SFT size during annealing. The results of annealing experiments on electron-irradiated Ni at 300 K are indicated in the paper, for comparison. We also have briefly discussed the positron response to the SFT-like structures.

► We study, by means of PAS, the evolution of vacancy defects in neutron-irradiated Ni. ► Three-dimensional vacancy clusters (3D-VCs) formed in cascades during irradiation at 330 K. ► 3D-VCs transform into SFTs and vacancy loops during annealing above 350 K. ► Shrink of SFTs shifts forward to higher annealing temperatures with dose level growth.