Performance of aged cement–polymer composite immobilizing borate waste simulates during flooding scenarios

An advanced composite of cement and water extended polyester based on the recycled Poly(ethylene terephthalate) waste was developed to incorporate the borate waste. Previous studies have reported the characterizations of the waste form (cement–polymer composite immobilizing borate waste simulates) after 28 days of curing time. The current work studied the performance of waste form aged for 7 years and subjected to flooding scenario during 260 days using three types of water. The state of waste form was assessed at the end of each definite interval of the water infiltration through visual examination and mechanical measurement. Scanning electron microscopy, infrared spectroscopy, X-ray diffraction and thermal analyses were used to investigate the changes that may occur in the microstructure of the waste form under aging and flooding effects. The actual experimental results indicated reasonable evidence for the durable waste form. Acceptable consistency was confirmed for the waste form even after aging 7 years and exposure to flooding scenario for 260 days.

► Developing of recycled Poly(ethylene terephthalate) waste to incorporate the borate waste. ► Performance of cemented waste form aged for 7 years and subjected to flooding scenario. ► SEM, X-ray diffraction, Thermal and FT-IR investigated the microstructure of cemented waste.