| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 1566967 | Journal of Nuclear Materials | 2011 | 12 Pages |
Samples of filtered particulates and sludges, formed from corroding magnesium alloy clad uranium metal (“Magnox”) fuel elements, collected from one of the legacy nuclear fuel storage ponds located at Sellafield (UK) were investigated by Environmental Scanning Electron Microscopy with Energy Dispersive X-Ray analysis (ESEM/EDX), micro-Raman spectroscopy and Fourier transform infra-red spectroscopy (FT-IR). ESEM imaging confirmed the dominant morphology to be clusters of interlocking platelets typical of brucite (Mg(OH)2). EDX analysis was suggestive of some conversion to the related phase, hydrotalcite (Mg6Al2(CO3)(OH)16·4H2O), due to elevated levels of Al associated with Mg. Other apparent morphologies were less commonly observed including flaky sheets, consistent with earlier stages of Magnox alloy corrosion. In a few specific cases, rods were also observed suggestive of some conversion to Mg-hydroxycarbonate phases. Discrete phases rich in U were also identified. Fluorescence in the Raman spectroscopy also indicated surface coatings of organic macromolecules and iron sulphide on hematite containing particles, attributed to microbial activity within the open air pond. Some specific differences in the solid phases between pond areas with differing conditions were apparent.
Graphical abstractSpent Magnox fuel corroding in-situ in storage ponds forms sludges comprised of brucite and other Mg based phases with uranium oxide particles.Figure optionsDownload full-size imageDownload as PowerPoint slideResearch highlights► Caracterization study of highly radioactive corroded Magnox sludges. ► Unique data from samples of actual corroded nuclear fuel. ► Combined electron microscopy and vibrational spectroscopy study. ► Analysis of particles from legacy spent fuel storage pond at Sellafield. ► Supports major UK decommissioning and nuclear clean up challenge.
