Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1787466 | Current Applied Physics | 2011 | 4 Pages |
Abstract
At monolayer coverage of Pd on Ru(0001) surface, the core-level spectra of Pd 3d shows a positive core-level shift of X-ray photoelectron spectroscopy (XPS) while the d-band center of valence band spectra moves away from Fermi level in comparison of bulk Pd(111). The modification of electronic structures, displayed in core-level and valence band XPS spectra can be explained with substrate-induced charge polarization effect in Pd layer, resulting in lowering average potential around atom.
► Ultrathin Pd films on Ru(0001) surface is investigated with XPS. ► Pd 3d shows a positive core-level shift while d-band center moves away from Fermi level. ► The charge polarization effect of Pd adlayer is estimated from XPS analysis.
Keywords
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Condensed Matter Physics
Authors
Yong Su Kim, Bongjin Simon Mun, Philip N. Ross,