Article ID Journal Published Year Pages File Type
1787689 Current Applied Physics 2011 4 Pages PDF
Abstract

Nanostructured Pt/CePO4 thin-film electrodes consisting of the Pt nanocrystallites and amorphous CePO4 were synthesized by sputtering, and the enhanced electrooxidation properties of methanol were investigated. Compared to a bare Pt electrocatalyst, the Pt/CePO4 nanocomposites exhibited remarkably higher activities. The improved catalytic activities were observed even after normalization by the electrochemical surface area. This can be explained by both the bi-functional effect of CePO4 and the modified electronic structure of Pt by the charge transfer from CePO4 to Pt.

Related Topics
Physical Sciences and Engineering Physics and Astronomy Condensed Matter Physics
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