Article ID Journal Published Year Pages File Type
178970 Electrochemistry Communications 2015 4 Pages PDF
Abstract

•This work shows a successful band-gap reduction in Ta3N5 nanotubes by W doping.•The doping process occurs in-situ during the anodic growth from a TaW substrate.•W doped Ta3N5 nanotubes provide enhanced PEC performance under AM 1.5 conditions.

Ordered W-doped Ta2O5 nanotube arrays were grown by self-organizing electrochemical anodization of TaW alloys with different tungsten concentrations and by a suitable high temperature ammonia treatment, fully converted to W:Ta3N5 tubular structures. A main effect found is that W doping can decrease the band gap from 2 eV (bare Ta3N5) down to 1.75 eV. Ta3N5 nanotubes grown on 0.5 at.% W alloy and modified with Co(OH)x as co-catalyst show ~ 33% higher photocurrents in photoelectrochemical (PEC) water splitting than pure Ta3N5.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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