Article ID Journal Published Year Pages File Type
179085 Electrochemistry Communications 2014 5 Pages PDF
Abstract

•Nanostructured ss- and dsDNA/PNIPA composites were synthesized.•Volume phase transition and DNA conformational transformation occur simultaneously.•Anodic guanine current significantly increases in physiological temperatures.•Both transformations are switchable.

Nanostructured DNA/poly(N-isopropylacrylamide) PNIPA composites were synthesized. DNA was noncovalently entrapped. A strongly enhanced electrooxidation current of DNA guanine was obtained due to cooperation of two temperature switchable effects: the volume phase transition of composites and conformational transition of DNA structure.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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