Article ID Journal Published Year Pages File Type
179187 Electrochemistry Communications 2014 4 Pages PDF
Abstract

•Non-manual electrochemically induced polymerization of benzoxazine derivatives•Controlled deposition of poly(benzoxazine) by optimized electrochemical pulse sequences•Entrapment of glucose oxidase in electropolymerized poly(benzoxazine) films

Water-soluble benzoxazine oligomers were synthesized by reacting bisphenol A, tetraethylenepentamine and formaldehyde. The pre-formed benzoxazine oligomers can be further electropolymerized from aqueous suspensions under formation of poly(benzoxazine)-based films on electrode surfaces. Integration of glucose oxidase in a poly(benzoxazine) film let to highly reproducible and stable biosensors. Poly(benzoxazines) are proposed as a new family of stable polymers for the design of enzyme electrodes.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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