| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 179487 | Electrochemistry Communications | 2013 | 4 Pages |
Abstract
Different amounts of Pt atoms were deposited onto the surface of Pd nanoparticles supported on carbon black by hydroquinone reduction method in anhydrous ethanol. Here, we surveyed electrochemical probing of surface compositions of Pd–Pt surface alloys. They were calculated from hydrogen desorption, carbon monoxide adlayer oxidation, and reduced carbon dioxide oxidation charges. The surface composition of Pt drastically increased up to Pt[0.3]/Pd/C (23.1 at.% of Pt) and then approached that of pure Pt with the moderate rate of increase.
► Pd–Pt core–shell nanoparticles with various ratios of Pt to Pd ► Reductive adsorption of carbon dioxide selective to Pt ► Electrochemical determination of surface composition of Pd–Pt bimetallic surfaces
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Tae-Yeol Jeon, Sung Jong Yoo, Yong-Hun Cho, Hee-Young Park, Yung-Eun Sung,