Nitroxyl radical self-assembled monolayers: Generalized lateral interactions model used with binary electrolyte mixture

The electrochemical behavior of redox centers on self-assembled monolayer (SAM) was interpreted through the generalized lateral interactions model when the electrolyte medium is composed of miscible solvents.Electrochemical behaviors of nitroxyl radical SAMs provide evidence of a linear dependence of interaction parameters with the ratio of the two solvents.

Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Generalized lateral interactions model can be used with binary electrolyte mixtures. ► The dependence of interaction parameters on the ratio of two solvents is linear.