| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 179775 | Electrochemistry Communications | 2012 | 4 Pages |
Abstract
This work establishes an experimental estimation of the full steady-state coverage of redox centers on self-assembled monolayers. The results demonstrate that the assessment of the full surface coverage and the adsorption kinetic from a Langmuir model impose drastic experimental conditions.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► The full steady-state coverage on SAMs is estimated from electrochemical data. ► This assessment imposes drastic experimental conditions. ► The adsorption free energy is clearly independent of the chain length. ► The rate of adsorption increases monotonously with chain length.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Olivier Alévêque, Pierre-Yves Blanchard, Tony Breton, Marylène Dias, Christelle Gautier, Eric Levillain,