| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 179836 | Electrochemistry Communications | 2012 | 4 Pages |
The electrodeposition and dissolution of Zn2+ have been investigated in 1-ethyl-3-methylimidazolium dicyanamide [emim][dca] ionic liquid to support the development of Zn-based secondary batteries. Cyclic voltammetry indicates that the zinc salt dissolved in the ionic liquid (IL) is a critical factor in the observed Zn/Zn2+ electrochemistry. The Zn2+ salt anions were found to have varying interaction strengths with the dissolved Zn2+ species in the order dicyanamide < sulfate < chloride < acetate. The concentration of water was found to be a crucial parameter for obtaining a uniform, dendrite free morphology when depositing zinc at a potential of − 2.15 V vs. Fc0/+. When deposited on glassy carbon, Zn(dca)2 in [emim][dca] displays high current densities and efficiencies appropriate for use in energy storage applications and has been found to allow the deposition of zinc metal in uniform, non-dendritic morphologies.
► Anion and H2O effects on Zn/Zn(II) electrochemistry in ionic liquid were investigated. ► Doping salt anion was found to drastically effect Zn redox electrochemistry. ► 3 wt% H2O was found to yield uniform, smooth zinc metal deposits in ionic liquid. ► Absence of water yields poor, porous zinc metal deposits. ► Zn(dca)2/ionic liquid electrolyte yields very high current densities (45 mA cm− 2).
