Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
180121 | Electrochemistry Communications | 2011 | 4 Pages |
The substitution of a small amount of Ga in the high-voltage spinel cathode LiMn1.5Ni0.42Ga0.08O4 leads to superior cyclability at room temperature and 55 °C along with higher rate capability with conventional electrolytes compared to that found with the LiMn1.5Ni0.5O4 cathode. The superior performance is attributed to the segregation of the inert Ga3+ ions to the surface during the synthesis process, providing a robust, more stable interface with the electrolyte at the high operating voltage (~ 4.7 V), along with the stabilization of the spinel structure with a disordering of the cations in the octahedral sites.
► Surface and depth-profile characterization by time-of-flight secondary ion mass spectroscopy. ► Superior elevated-temperature cyclability and rate capability for 5 V spinel cathodes. ► Cost-effective, one-step surface decoration of high-voltage cathodes by dopant ions.