Article ID Journal Published Year Pages File Type
180835 Electrochemistry Communications 2010 4 Pages PDF
Abstract

Protic ionic liquids (PILs) were used as novel electrolyte for carbon-based supercapacitors. The cyclic voltammograms in three-electrode cells show reversible redox humps, revealing pseudo-faradaïc charge transfer. Oxidative treatment of activated carbon enriches the surface functionality and leads to a higher capacitance owing to a stronger pseudo-faradaïc contribution. The capacitors using PILs demonstrate a higher voltage window than with aqueous H2SO4, while keeping the same values of capacitance, and being able to operate at lower temperature. A combination of activated carbons and PILs holds promise for improving the energy characteristics of supercapacitors.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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