| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 181010 | Electrochemistry Communications | 2008 | 4 Pages |
Electrodeposition of aluminium within an alumina nano-structured template, for use as high surface area current collectors in Li-ion microbatteries, was investigated. The aluminium electrodeposition was carried out in the ionic liquid 1-ethyl-3-methylimidazolium chloride:aluminium chloride (1:2 ratio). First the aluminium electrodeposition process was confirmed by combined cyclic voltammetry and electrochemical quartz crystal microbalance measurements. Then, aluminium was electrodeposited under pulsed-potential conditions within ordered alumina membranes. A careful removal of the alumina template unveiled free standing arrays of aluminium nano-rods. The nano-columns shape and dimensions are directly related to the template dimensions. To our knowledge, this is the first time that direct electrodeposition of aluminium nano-pillars onto an aluminium substrate is reported.
