Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
181381 | Electrochemistry Communications | 2009 | 4 Pages |
We report the first fabrication of large-area Cu nano-octahedra with well-defined shape, good monodispersity and uniform distribution on a gold film substrate (GFS) by a very simple, rapid and cost-effective low-potential electrodeposition (LPED) technique. Different from general surfactant-assisted electrochemical approaches, LPED is an additive-free strategy that exploits the subtle surface energy differences among various crystallographic planes of metals themselves. The size of the octahedra depends on deposition time and is adjustable over a wide range. The shape evolution is found to be remarkably different from that of octahedral particles formed in solution. A formation mechanism is proposed for the unique evolution of Cu octahedra as resulting from the anisotropic growth under appropriate applied potentials.