Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
182027 | Electrochemistry Communications | 2008 | 4 Pages |
Abstract
The salt films formed on metal surfaces dissolving inside artificial corrosion pits formed in 1 M HCl have been probed with synchrotron X-ray diffraction. NiCl2 · 6H2O is the main phase in the salt film on nickel, whereas salt films on both iron and 316 L stainless steel are predominantly FeCl2 · 4H2O. However, the salt film on iron has a very fine homogeneous crystallite size whereas that on stainless steel is much coarser. The potential-dependence of the film formed on iron has been determined.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Trevor Rayment, Alison J. Davenport, Andrew J. Dent, Jean-Philippe Tinnes, Richard J.K. Wiltshire, Christopher Martin, Graham Clark, Paul Quinn, J. Fred W. Mosselmans,