Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
182154 | Electrochemistry Communications | 2008 | 4 Pages |
Abstract
A thin-layer of polypyrrole (PPy) film, immobilized with neutral 5,10,15,20-tetraphenylporphyrinato cobalt (II) (Co-TPP), was successfully and uniformly deposited onto mesoporous carbon fibre paper (CFP) via vapor-phase polymerization. The resulting PPy/Co-TPP-modified carbon fibre paper (PPy/Co-TPP-CFP) electrode was characterized by cyclic voltammetry, SEM and EDX-ray mapping. Its electrochemical stability and long-term electrocatalytic performance were investigated in a half-fuel cell testing system. The electrode displayed significant electrocatalytic performance for oxygen reduction at 0.0 V (vs. Ag/AgCl), with notable long-term stability.
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Authors
Weimin Zhang, Jun Chen, Pawel Wagner, Gerhard F. Swiegers, Gordon G. Wallace,