Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
182368 | Electrochemistry Communications | 2008 | 4 Pages |
Abstract
A “green” method for production of diethyl aminomalonate was presented by electrocatalytic reduction of diethyl oximinomalonate (DEOM) to diethyl aminomalonate in the acetic acid and sodium acetate medium at the surface of Ti/nanoporous TiO2 electrode. The heterogeneous catalytic redox behaviour of a nanoporous TiO2 film electrode surface was investigated by cyclic voltammetry (CV). A comparison of the CV recorded in the absence and in the presence of DEOM confirmed the catalytic reduction of DEOM by Ti(IV)/Ti(III) redox system on the nanoporous TiO2 film surface.
Related Topics
Physical Sciences and Engineering
Chemical Engineering
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Authors
Daobao Chu, Mai Xu, Jia Lu, Peng Zheng, Guoxu Qin, Ximei Yuan,