Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
182537 | Electrochemistry Communications | 2007 | 6 Pages |
Two different approaches were tried for an improvement of the cycle performance of Li–S cells: (1) A mixed polymer binder system of polyvinyl pyrrolidone (PVP) and polyethyleneimine (PEI) was developed to maintain the initial morphology of the carbon electrodes, the positive electrode of the Li–S cells, during charge–discharge cycles; (2) a tetrabutylammonium (TBA)-based mixed salt system was applied to an organic liquid electrolyte of the Li–S cells to change certain chemical reactions of polysulfides in the electrolyte solutions. The Li–S cells with PEI showed a significant improvement in cycle performance as well as in discharge capacity, compared with the Li–S cells using PVP only. The discharge capacity at the 50th cycle was found to be ∼580 mAh/g-sulfur, 83% of an initial capacity (∼720 mAh/g-sulfur), at a high current density of 2.0 mA cm−2. It was observed that the Li–S cells with a mixed electrolyte of 0.5 M LiCF3SO3/0.5 M TBAPF6 did not show a distinct improvement in the aspect of discharge capacity. The Li–S cells, however, showed a significant enhancement in the cycle life characteristics much better than that of Li–S cells with 1.0 M LiCF3SO3.