Article ID Journal Published Year Pages File Type
182592 Electrochemistry Communications 2006 5 Pages PDF
Abstract

The oxygen reduction reaction (ORR) on carbon-supported Pt–Co alloy nanoparticles has been investigated. As-prepared Pt–Co alloy nanoparticles exhibit a single-phase disordered structure and have a very small particle size. Such alloy catalysts exhibit an enhancement of a factor of ca. 1.3–3.2 in Pt mass activity and of a factor of ca. 1.2–2.2 in the specific activity for the ORR when compared to Pt/C catalyst. The enhanced electrocatalytic activity is attributed to the favorable Pt–Pt mean interatomic distance caused by alloying and to the high dispersion of the alloy catalysts.

Related Topics
Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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