Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
182742 | Electrochemistry Communications | 2006 | 4 Pages |
Abstract
The ion transfer reaction across liquid|liquid interface present at carbon paste electrode prepared with hydrophobic room temperature ionic liquid (RTIL)-1-decyl-3-methylimidazolum bis(trifluoromethylsulfonylimide) as a binder is reported. Ion transfer was forced by generation of tert -butylferrocenium cation from neutral substrate present in RTIL phase. This process exhibits selectivity towards hydrophobic anions like ClO4- or PF6- and it is more efficient than in the case of carbon paste electrode based on polar solvent.
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Authors
Galyna Shul, Juliette Sirieix-Plenet, Laurent Gaillon, Marcin Opallo,