Article ID Journal Published Year Pages File Type
182742 Electrochemistry Communications 2006 4 Pages PDF
Abstract

The ion transfer reaction across liquid|liquid interface present at carbon paste electrode prepared with hydrophobic room temperature ionic liquid (RTIL)-1-decyl-3-methylimidazolum bis(trifluoromethylsulfonylimide) as a binder is reported. Ion transfer was forced by generation of tert  -butylferrocenium cation from neutral substrate present in RTIL phase. This process exhibits selectivity towards hydrophobic anions like ClO4- or PF6- and it is more efficient than in the case of carbon paste electrode based on polar solvent.

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Physical Sciences and Engineering Chemical Engineering Chemical Engineering (General)
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