| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 185704 | Electrochimica Acta | 2014 | 10 Pages |
Abstract
The coupling of faradaic and charging currents is shown, by numerical simulation, to result in impedance responses showing high-frequency frequency dispersion that resembles pseudo-Constant-Phase-Element (CPE) behavior. The results show that coupling of faradaic and charging currents should be considered when modeling the impedance response for systems influenced by mass transfer, even for large concentrations of supporting electrolyte.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Chemical Engineering (General)
Authors
Shao-Ling Wu, Mark E. Orazem, Bernard Tribollet, Vincent Vivier,