Article ID Journal Published Year Pages File Type
1884802 Radiation Physics and Chemistry 2007 8 Pages PDF
Abstract
Positron annihilation spectroscopy has been used to measure the ortho-positronium lifetime variation with respect to the temperature in an 80-nm polystyrene film on Si in different depths. The surface and interface glass transition temperatures were found to be significantly suppressed by 18 and 12 K at the depth of 5 and 70 nm from the surface, respectively. The observed Tg-depth dependence is interpreted as a different degree of free-volume distributions at the surface and the interface with Si.
Related Topics
Physical Sciences and Engineering Physics and Astronomy Radiation
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