Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1886437 | Radiation Physics and Chemistry | 2012 | 12 Pages |
Abstract
⺠Crystalline Rochelle salt was X-irradiated at 10 K and studied using EMR techniques. ⺠Interpretation of present and previous data was aided by cluster DFT calculations. ⺠Regioselective reduction and non-selective oxidation apparently occur at 10 K. ⺠Thermally induced free radical reactions were followed to provide reaction mechanisms. ⺠A complete solid-state radical reaction scheme for (di)carboxylic acids is proposed.
Related Topics
Physical Sciences and Engineering
Physics and Astronomy
Radiation
Authors
Einar Sagstuen, Eli Olaug Hole, Anders Lund,