Article ID Journal Published Year Pages File Type
1886437 Radiation Physics and Chemistry 2012 12 Pages PDF
Abstract
► Crystalline Rochelle salt was X-irradiated at 10 K and studied using EMR techniques. ► Interpretation of present and previous data was aided by cluster DFT calculations. ► Regioselective reduction and non-selective oxidation apparently occur at 10 K. ► Thermally induced free radical reactions were followed to provide reaction mechanisms. ► A complete solid-state radical reaction scheme for (di)carboxylic acids is proposed.
Related Topics
Physical Sciences and Engineering Physics and Astronomy Radiation
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