Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
1891520 | Radiation Physics and Chemistry | 2013 | 9 Pages |
Benzaldehyde and its derivatives efficaciously oxidize in aqueous solutions α-hydroxyl-containing carbon-centered radicals (α-HCR) of various structures, suppressing thereby the radical recombination and fragmentation reactions. The compounds containing cinnamic moieties are capable of adding α-hydroxyethyl radicals (α-HER) to the carbon–carbon double bonds conjugated with the aromatic system to form molecular products identifiable by mass spectrometry. On radiolysis of aqueous ethanol solutions, reduction of α-HER by aromatic alcohols and acids has been shown to proceed via formation of their adducts with hydrated electron species.
► Benzaldehydes oxidize α-hydroxyl-containing carbon-centered radicals. ► Phenylproranoids add α-hydroxyethyl radicals to the activated C=C bonds. ► Aromatic alcohols and acids form radical-adducts with eaq− in aqueous solutions.