Article ID Journal Published Year Pages File Type
2028671 Steroids 2011 7 Pages PDF
Abstract
► 1,8-bis(Trimethylsilyl)octa-2,6-diene and ethylene ketals afford 1,3-divinylcyclopentanes precursors of D-ring of steroids. ► A four step synthesis of 13-bromophenyl gonatrienes is described. ► (8β,9β,14β)-17β-Acetyl-13β-p-bromophenyl-11,11-di(methoxycarbonyl)-3-methoxygona-1,3,5(10)-triene.
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