Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
2028671 | Steroids | 2011 | 7 Pages |
Abstract
⺠1,8-bis(Trimethylsilyl)octa-2,6-diene and ethylene ketals afford 1,3-divinylcyclopentanes precursors of D-ring of steroids. ⺠A four step synthesis of 13-bromophenyl gonatrienes is described. ⺠(8β,9β,14β)-17β-Acetyl-13β-p-bromophenyl-11,11-di(methoxycarbonyl)-3-methoxygona-1,3,5(10)-triene.
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Authors
Nicolas Galy, Maurice Santelli,