| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 26366 | Journal of Photochemistry and Photobiology A: Chemistry | 2016 | 6 Pages |
•The two photon absorption cross section of DPATSP and its N-methyl derivative have been estimated using Z scan technique.•Nonlinear refraction and the TPA cross section (σ2) increases by increasing the acceptor strength in quazi-octupolar molecules.•The Z-scan technique is shown to have a clear advantage over the TPIF method for TPA estimation of weakly fluorescent samples.
Two photon absorption (2PA) cross sections of two quasi-octupolar molecules (E,E,E)-2,4,6-tris [2-(4-N,N-diphenylaminophenyl)vinyl]pyridine (DPATSP) and (2,4,6-tris((E)-4-(diphenylamino)styryl)-1-methylpyridine-1-ium iodide, DPATSP-Me) have been estimated. It has been found that by introducing the pyridinium ion, the 2PA cross section of DPATSP-Me increases with respect to the parent molecule, DPATSP. Z-scan experiments on the two samples reveal that DPATSP-Me is a better candidate for optical limiting applications.
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