| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 26534 | Journal of Photochemistry and Photobiology A: Chemistry | 2012 | 9 Pages |
β-Cyclodextrin is chemically modified to selectively introduce an acridinedione moiety on the primary face. The synthesis involves the substitution of one of the primary hydroxyl groups of β-cyclodextrin by a tosyl group which facilitates the introduction of an ethylene diamine modification which is finally condensed to a tetraketone. The acridinedione modified β-cyclodextrin thus obtained was fully characterized by IR, NMR and Mass spectrometry. The photophysical properties of the compound were also analyzed. The potential of the modified β-cyclodextrin to act as an energy donor in FRET was investigated with a suitable acceptor.
Graphical abstractFigure optionsDownload full-size imageDownload as PowerPoint slideHighlights► An acridinedione modified β-cyclodextrin was synthesized and characterized. ► The modified compound well resembled the native acridinedione dyes in fluorescent properties. ► An efficient FRET process was observed with safranine dye as acceptor and the modified compound as the energy donor. ► Higher efficiency of FRET was due to the inclusion of the acceptor into the cavity of β-cyclodextrin.
