| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 27081 | Journal of Photochemistry and Photobiology A: Chemistry | 2012 | 7 Pages |
An α-disulfone cationic photoinitiator called 4-tolyl methyl disulfone was synthesized and characterized by UV–vis absorption spectroscopy, LCMS, IR and NMR. Eight vinyl ether monomers were chosen to study the kinetics of photopolymerization by real-time infrared spectroscopy (FT-IR). It showed that 4-tolyl methyl disulfone was an effective cationic photoinitiator. The rate of polymerization and ultimate conversion increased with increase of 4-tolyl methyl disulfone concentration and light intensity.
► Under UV light, photolysis occurred for TMDS in methanol to form sub-sulfonic acids. ► TMDS has a maximal absorption of 237 nm in ethanol due to π–π* transition with ɛmax = 2.73 × 104 L mol−1 cm−1. ► Eight vinyl ether monomers were chosen to study the kinetics of photopolymerization by real-time infrared spectroscopy (FT-IR). ► TMDS was an effective cationic photoinitiator. Both rate of polymerization and final conversion was increased with increase in TMDS concentration and light intensity.
