Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
27147 | Journal of Photochemistry and Photobiology A: Chemistry | 2010 | 9 Pages |
Abstract
A variety of Biginelli 5-acetyl-3,4-dihydropyrimidin-2(1H)-ones are efficiently oxidized to their corresponding pyrimidin-2(1H)-one derivatives upon UV irradiation under argon atmosphere in chloroform solution. The nature of the additional substituent on the phenyl ring located on C-4 of the heterocyclic ring influences the rate of reaction. An electron-transfer induced photoreaction is proposed based on the formation of HCl and CH2Cl2.
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Authors
Hamid Reza Memarian, Asadollah Farhadi, Hassan Sabzyan, Mousa Soleymani,