| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 27365 | Journal of Photochemistry and Photobiology A: Chemistry | 2011 | 4 Pages |
Abstract
Infrared laser dissociation of 2-chloroethyltrifluorosilane has been studied in light of silicon isotopes separation. The reaction occurs via beta-elimination mechanism to yield ethylene and chlorotrifluorosilane as products. The dissociation has a relatively low energy barrier what was confirmed by high-level quantum chemical calculations. High enrichment of 30Si isotope was demonstrated.
► Infrared laser induces a reaction of 2-cloroethyltrifluorosilane. ► The reaction has a molecular beta-elimination mechanism. ► Silicon isotopes separation is realizable.
Keywords
Related Topics
Physical Sciences and Engineering
Chemical Engineering
Bioengineering
Authors
Petr S. Dementyev, Anton S. Nizovtsev, Evgenii N. Chesnokov,