Article ID Journal Published Year Pages File Type
27750 Journal of Photochemistry and Photobiology A: Chemistry 2009 6 Pages PDF
Abstract

An unique photochemical hydration of trans-stilbene, trans-3-methoxystilbene and trans-anethole was observed inside cyclodextrin nanocavity in water. An excited-state proton transfer from cyclodextrin hydroxyl groups via a carbocation intermediate, which is stabilized by cyclodextrin secondary hydroxyl groups, is proposed.

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