| Article ID | Journal | Published Year | Pages | File Type |
|---|---|---|---|---|
| 27867 | Journal of Photochemistry and Photobiology A: Chemistry | 2012 | 7 Pages |
The new triphenylene 1,3-diketone (1-triphenylen-2-yl-3-trifluoroacetylacetone (TphTA)) and its europium complexes were synthesized. The preliminary data on photophysical properties of Eu(TphTA)3(H2O)(C2H5OH) (1), Eu(TphTA)3(TOPO)(H2O) (2), Eu(TphTA)3(TOPO)2 (3) and Eu(TphTA)2NO3(TOPO)2 (4) are reported. Addition of a tri-n-octylphosphine oxide (TOPO) co-ligand to the europium diketonate complex removes water molecules from the coordination sphere, that leads to a significant increase of the photoluminescence quantum yield. The behavior of complexes 3 and 4 in nematic liquid crystal was investigated.
Graphical abstractTernary Eu(III) complex involving two 1,3-diketonate ligands, nitrate anion and two tri-n-octyl phosphinoxide co-ligands, and its photoluminescence spectrum.Figure optionsDownload full-size imageDownload as PowerPoint slideHighlights► Tri-n-octylphosphine oxide as auxiliary ligand enhances the photoluminescence quantum yield 3-, 6-fold of the Eu(III) complex. ► The orientation of triphenylene unit is parallel to the long axis of the nematic phase. ► Nematic phases appended with Eu(III) complexes are luminescent.
