Article ID Journal Published Year Pages File Type
27953 Journal of Photochemistry and Photobiology A: Chemistry 2007 6 Pages PDF
Abstract

A photochromic switching copolymer was synthesized by typical radical copolymerization of 2-(9H-carbazol-9-yl) ethyl methacrylate, a vinyl monomer having a spironaphthoxazine residue. It reversibly changed the fluorescent intensity by alternative irradiation with ultraviolet and visible light probably due to the photoinduced electron transfer (PET) between carbazoles and the open form of spirooxazine (SPO) moiety. By the observation of photoresponsive viscosity and conductivity changes, it was confirmed that the copolymer could exhibit excellent viscosity and conductivity switching behaviors.

Related Topics
Physical Sciences and Engineering Chemical Engineering Bioengineering
Authors
, , , ,