Article ID Journal Published Year Pages File Type
28867 Journal of Photochemistry and Photobiology A: Chemistry 2007 7 Pages PDF
Abstract

Hybrid monomer 3-(1-propenyl)oxypropyl acrylate, combining easy free radical and fast cationically polymerizable group, was synthesized by phase-transfer catalyzed substitution, isomerization and subsequently esterification. Its photopolymerization kinetics was monitored by Fourier transform real-time infrared spectroscopy (FTIR) with a horizontal sample holder. The results indicated that hybrid monomer showed inter-group interaction in photopolymerization process, which decreased moisture sensitivity to cationic photopolymerization process, and represented higher efficiency of photopolymerization when compared with blend system.

Related Topics
Physical Sciences and Engineering Chemical Engineering Bioengineering
Authors
, , ,