Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
29242 | Journal of Photochemistry and Photobiology A: Chemistry | 2007 | 4 Pages |
Abstract
2-Methylol-thioxanthone (TX-M) was synthesized and characterized as a new photoinitiator. Photopolymerization experiments were performed with methyl methacrylate and also trimethylolpropanetriacrylate (TMPTA) as a multifunctional monomer in the presence of TX-M with N-methyl diethanol amine. Polymerization did not occur in an air atmosphere with TX-M without adding MDEA. The inhibiting effect of oxygen on the rate of polymerization was observed to be due to quenching of the triplet radicals by the carbonyl compound (TX-M).
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Authors
Gokhan Temel, Nergis Arsu,