Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
4754042 | Journal of Photochemistry and Photobiology A: Chemistry | 2016 | 24 Pages |
Abstract
Complementary to the previous assignment of the first, second, and fourth binding sites of human serum albumin (HSA) for 2-anthracenecarboxylate (AC) and the subsequent mediation of AC photocyclodimerization, the site-specific inhibition of the enantiodifferentiation by xenon allowed us to assign the remaining third and fifth AC-binding sites to subdomains IB and IIIB, respectively. This study reveals a clearer picture of the binding and photochirogenic behavior of HSA and further expands the scope of bio-supramolecular photochirogenesis.
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Authors
Masaki Nishijima, Tamara C.S. Pace, Cornelia Bohne, Tadashi Mori, Yoshihisa Inoue, Takehiko Wada,