Article ID Journal Published Year Pages File Type
5009141 Sensors and Actuators B: Chemical 2017 8 Pages PDF
Abstract

•The sensitivity and conductivity of WO3 both were enhanced by adding of KOH or Au NPs.•Adsorption dynamic analysis was used to study the water molecules adsorption on KOH- and Au NPs-added WO3.•KOH adding had higher sensitivity than that of Au NPs.•KOH-added WO3 exhibited greatest sensitivity, lowest hysteresis and shortest response time over a wide range of humidity.

Impedance-type humidity sensors were fabricated from WO3 particles to which had been added KOH or Au nanoparticles (Au NPs). The humidity-sensing (sensitivity and linearity) and electrical properties of the WO3 were improved. Adsorption dynamic analysis and molecular mechanical calculations revealed that the sensitivity of KOH-added WO3 exceeded that of Au NPs-added WO3. The sensor that was made of the KOH-added WO3 exhibited favorable impedance, high sensitivity, good linearity, low hysteresis, a short response/recovery time and high long-term stability over the studied humidity range. Complex impedance spectra were used to investigate the humidity-sensing mechanism of the KOH-added WO3.

Related Topics
Physical Sciences and Engineering Chemistry Analytical Chemistry
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