Article ID | Journal | Published Year | Pages | File Type |
---|---|---|---|---|
5009637 | Sensors and Actuators B: Chemical | 2017 | 8 Pages |
â¢A new bifunctional fluorescent chemosensor 3TN bearing oligothiophene was developed.â¢3TN shows fluorescence “turn-on/turn-off” characteristic responses to Hg2+ and Cu2+.â¢The Hg2+/Cu2+ detection was highly reversible, selective and sensitive.â¢The response time to Hg2+/Cu2+ ions is less than 2 min.
A novel oligothiophene-phenylamine based Shiff-base 3TN was successfully developed as a dual fluorescent chemosensor for the rapid detection of Hg2+ and Cu2+ ions in THF/H2O (7/3, v/v) solution. Interestingly, 3TN upon interaction with various metal cations displays highly selective fluorescent turn-on response to Hg2+ and selective fluorescent turn-off response to Cu2+. The recognition process was highly reversible and completed within 2Â min. The 1:1 binding modes (3TN/Hg2+ and 3TN/Cu2+) were proved by fluorescence measurements and FT-IR. Sensor 3TN also exhibits high anti-interference performance towards Hg2+/Cu2+ over other metal ions in a wide pH range. Moreover, the quite low detection limit was found to be 1.16Â ÃÂ 10â7Â M for Hg2+ and 7.06Â ÃÂ 10â8Â M for Cu2+. Therefore, these investigated results demonstrates that sensor 3TN has great potential to detect Hg2+ and Cu2+ ions in environmental analysis systems.
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